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Showing posts from 2020

Is there a limiting current in alkaline water electrolysis and why does the cathode level rise?

             1.       Modeling and Experiments of Binary Electrolytesin the Presence of Diffusion, Migration, and Electro-Osmotic Flow . Haverkort, J. W. (2020).  Physical Review Applied, 14(4), 044047.                        2.        Electro-osmotic flow and the limiting current in alkaline water electrolysis . Haverkort, J. W., & Rajaei, H. (2020). Journal of Power Sources Advances, 6, 100034.  Recommended with a Commentary by Dr. ir. Willem Haverkorts, Delft University of Technology. Read the full commentary in  PDF format

Small, smaller, smallest

           1.      Critical Knowledge Gaps in Mass Transport through Single-Digit Nanopores: A Review and Perspective Authors: Samuel Faucher, Narayana Aluru, Martin Z. Bazant, Daniel Blankschtein, Alexandra H. Brozena John Cumings, J. Pedro de Souza, Menachem Elimelech,  Razi Epsztein, John T. Fourkas, Ananth Govind Rajan, Heather J. Kulik, Amir Levy, Arun Majumdar, Charles Martin, Michael McEldrew, Rahul Prasanna Misra, Aleksandr Noy, Tuan Anh Pham, Mark Reed, Eric Schwegler, Zuzanna Siwy, YuHuang Wang, and Michael Strano,  The Journal of Physical Chemistry C ,  123 (35), 21309-21326,   DOI: 10.1021/acs.jpcc.9b02178 Recommended with a Commentary by Mark Aarts, AMOLF Read the full commentary in  PDF format

Gaining insight into the electrical double layer from simultaneous measurements

           1.      A set-up for simultaneous measurement of second harmonic generation  and streaming potential and some test applications ,  Authors: Johannes L ü tzenkirchen, Tim Scharnweber, Tuan Ho, Alberto Striolo,  Marialore Sulpizi, Ahmed Abdelmonem,  Journal of colloid and interface science ,  529 , 294-305. Recommended with a Commentary by Remco Hartkamp, Delft University of Technology Read the full commentary in  PDF format

New Book: Physics of Electrochemical Processes

The past months have been unprecedented for many people around the world, and most were asked to work from home for long periods of time. Though of course we are happy that slowly things are improving, one positive thing did come out of the past months, which is that Maarten Biesheuvel (Wetsus) and Jouke Dykstra (Wageningen University) started writing the book they always wanted to write. The book has now over 300 pages, and is available as a pre-release free of charge from the website www.physicsofelectrochemicalprocesses.com . The book covers many of the topics related to Ionics and Iontronics, including membrane transport (electrodialysis, reverse osmosis) using 1D and 2D models, as well as the DLVW-theory for colloidal interaction, the physics of electrowetting, EDL theories (Frumkin, Donnan, GCS), bio-electrochemical processes, heat effects including electrostatic cooling, and incorporation of acid-base reactions in combined mass transport and reaction modeling. The authors ho...

Will we ever understand the long-range decay of concentrated electrolytes?

           1.      Correlation Length in Concentrated Electrolytes: Insightsfrom All-Atom Molecular Dynamics Simulations ,  Authors: Samuel Coles, Chanbum Park, Rohit Nikam, Matej Kanduč, Joachim Dzubiella, Benjamin Rotenberg ,   J. Phys. Chem. B 2020, 124, 9, 1778–1786      2.      The Electrostatic Screening Length in ConcentratedElectrolytes Increases with Concentration ,  Authors: Alexander Smith, Alpha A. Lee, and Susan Perkin,  J. Phys. Chem. Lett. 2016, 7, 12, 2157–2163         3.      Long-range Electrostatic Screening in Ionic Liquids ,  Authors: Matthew A. Gebbie, Howard A. Dobb, Markus Valtiner, and Jacob N. Israelachvi,  PNAS June 16, 2015 112 (24) 7432-7437 Recommended with a Commentary by MSc. Peter Cats, Institute for Theoretical Physics, Utrecht University Read the full commentary in  PDF format

Oscillating Electric Fields in Liquids Create a Long-Range Steady Field

    1. Oscillating Electric Fields in Liquids Create a Long-Range Steady Field , Authors: S.M.H. Hashemi Amrei, Scott C. Bukosky, Sean P. Rader, William D. Ristenpart, Gregory H. Miller,  Physical review letters ,  121 (18), 185504. Recommended with a Commentary by by Alexander Barnaveli,  ITF, Utrecht University Read the full commentary in  PDF format

Nanopipettes as probes of the surface charge

    1.  Nanopipette delivery: influence of surface charge ,  Authors: Wenqing Shi, Niya Sa, Rahul Thakar and Lane A. Baker,  Analyst, 2015, 140 , 4835     2. Scanning Ion Conductance Microscopy: Quantitative Nanopipette Delivery−Substrate Electrode Collection Measurements and Mapping ,  Authors: Baoping Chen, David Perry, Ashley Page, Minkyung Kang, and Patrick R. Unwin,  Anal. Chem. 2019, 91 , 2516−252 4 Recommended with a Commentary by by Sanli Faez, Nanophotonics, University of Utrecht. Read the full commentary in  PDF format

How diffuse is the electrical double layer?

    1. Structure of the Electrical Double Layer Revisited: Electrode Capacitance in Aqueous Solutions ,  Authors: Mahmoud Khademi and Dominik P. J. Barz ,  Langmuir   Article ASAP Recommended with a Commentary by by Rob Lammertink and Jeff Wood,  Soft matter, Fluidics and Interfaces (SFI), University of Twente. Read the full commentary in  PDF format

Colloidal particle transportation by salt gradient and its applications

    1.  Diffusiophoresis in one-dimensional solute gradients , Authors: Jesse T. Ault, Patrick B.  Warren, Sangwoo Shin, Howard A. Stone, Soft Matter, 2017,13, 9015-9023     2.  Low - Cost Zeta Potentiometry Using Solute Gradient s , Authors: Sangwoo Shin Jesse T. Ault Jie Feng Patrick B. Warren Howard A. Stone, Advanced Materials 2017, 29, 1701516     3.  Accumulation of Colloidal Particles in Flow Junctions Induced by Fluid Flow and Diffusiophoresis , Authors: Sangwoo Shin, Jesse T. Ault, Patrick B. Warren, Howard A. Stone, PHYSICAL REVIEW X 2017, 7, 041038 Recommended with a Commentary by Zhu Zhang, Nanophotonics Universiteit Utrecht. Read the full commentary in  PDF format

Understanding of the specific ion effects at solid surface by hybrid first principles/continuum simulations and experiments

    1.   Specific ion effects at graphitic interfaces , Authors: C. Zhan, M. R. Cerón, S. A. Hawks, M. Otani, B. C. Wood, T. A. Pham, M. Stadermann and P. G. Campbell,  Nature Communications, 2019, 10, 4858 Recommended with a Commentary by Cheng Lian, ITF, Utrecht University Read the full commentary in  PDF format

Microscopic description of Stern layer dynamics involving chemical reactions and non-ideal electrolytes

    1. Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics , Author: M. Bazant, Accounts of chemical research 46.5 (2013): 1144-1160     2.  Versatile electrification of two-dimensional nanomaterials in water , Authors: B. Grosjean, M. Bocquet, R. Vuilleumier, Nature communications, 10(1), 1-8 Recommended with a Commentary by Willem Boon, ITF, Utrecht University Read the full commentary in PDF format